HEALTH AND SAFETY 3
FRITS
Bath Potters' Supplies
CALUCIUM BORATE FRIT
MATERIAL SAFETY DATA SHEET
Identification of the preparation/Supplier reference
Trade Name Dry Ground Frit- 362642
Chemical name Frit.
Synonyms Calcium Borate Frit, HM192
Supplier
Bath Potters Supplies, Unit 18, Fourth Avenue, Westfield Trading Estate,
Radstock, Nr. Bath. BA3 4XE
Emergency numbers Tel: 01761 411077; Fax: 01761 414115
Internet: sales@bathpotters.co.uk
2. Composition
Component CAS EINECS % of composition
Frits, chemicals 65997-18-4 2660476 100
3. Health Hazard Identification
Inhalation Excessive exposure may cause symptoms of chronic lung disease.
Ingestion Product of low solubility in body fluids and likely to be of low acute toxicity.
Eyes May cause physical irritation and inflammation.
Skin Not a primary irritant. Any abrasive powder may give minor irritation.
4. First Aid Measures
Inhalation
Remove patient to fresh air, loosen tight clothing and seek medical attention.
Ingestion
Do not induce vomiting, seek medical advice.
Eyes
Wash immediately with copious amounts of water. Seek medical attention is irritation persists.
Skin
Wash affected areas with water. If irritation persists, seek medical attention
5. Fire Fighting Measures
Extinguishing Media
Suitable for surrounding fire conditions.
The product is not explosive or combustible. Standard fire fighting techniques only are required, i.e. water, sand, carbon dioxide, chemical foam extinguishers etc.
Special Exposure hazard
None.
Protective equipment
None other than required for surrounding fire conditions.
6. Accidental Release Measures
Leaks & Spills
Protective equipment
Remove dry materials either by a vacuum cleaner fitted with an efficient particulate filter or by damping down and scooping in to a receptacle.
Respiratory protective equipment.
7. Handling & Storage
Handling
Do not eat, drink, or smoke in areas where the material is used. Wash thoroughly after handling the material
Local exhaust ventilation is recommended to comply with occupational exposure limits (refer to Guidance Note EH40 - latest edition)
Storage
Store in dry area
8. Exposure Control/Personal protective Equipment
Engineering controls
Adequate ventilation should be provided so that Occupational Exposure Limits are not exceeded. Local Exhaust Ventilation is recommended
Personal protective equipment
Where LEV is not practicable and exposure is likely to be excessive, approved respiratory protection to CEN standards prEN 140, 141, 143 or 149 should be worn. Protective gloves and overalls are recommended for prolonged contact.
9. Physical & Chemical properties
Appearance & Odour
White powder, odourless
Flash point (ºC)
Not applicable
Flammability
Not applicable
Explosive properties
Non-explosive
Oxidising properties
Specific gravity
None
3-5
pH value
7 (Insoluble in water)
Melting point (ºC)
Not available
10. Stability & Reactivity
Chemical stability
The material is stable
Conditions/materials to avoid
None known
Hazardous decomposition products
None known
Hazardous polymerisation products
None
11. Toxicology Information
Acute toxicology
LD50 Oral >2000 mg/kg
LD50 Dermal Not known
LD50 Inhalation Not known
Health effects
Prolonged or repeated exposure above Occupational Exposure Standards may cause fibrosis of the lungs.
12. Ecological information
Ecotoxicity
Not known.
Persistence
Chemically stable and will persist in the environment.
13. Disposal
Dispose in accordance with current waste Disposal regulations (for UK - Control of Pollution (Special Waste) Regulations 1996). Landfill is the most appropriate method.
14. Transport Information
UN/SI No.
Not classified
UN Class
Not classified
Packing group
Not classified
Road UK ADR
Not classified
Not classified
Sea IMO
Not classified
Air ICAO
Not classified
15. Regulatory information
EC Supply Labelling
None required by directive 88/379/EEC and subsequent amendments.
R-Phrases
None.
S-Phrases
Optional for dusty powders:
S20/21 When using do not eat, drink or smoke.
S38 In case of insufficient ventilation wear suitable respiratory equipment.
UK Occupational exposures limits*
Dusts: Total inhalable
respirable
Mg/m3 8 hr TWA % in product
10
5
* refer to HSE Guidance note EH40
In accordance with the H.S.E. Approved Code of Practice for CHIP, the recipient is reminded of their obligations under both the Health and Safety at Work Act (HSWA) and the Control of Substances Hazardous to Health Regulations (COSHH), and that the information in any safety data sheet does not constitute the user’s assessment of workplace risk.
16. Other information
General industrial hygiene practices are recommended when handling and using this product.
COSHH ACOP: H.S.C. Approved Code of Practice for the Control of Substances Hazardous to Health Regulations 1994.
CHIP 96: Chemicals (Hazard Information and Packaging for Supply) Regulations 1996.
CHIP SDS ACOP: H.S.C. Approved Code of Practice for Safety Data Sheets in accordance with regulation 6 of the CHIP regulations.
HSE EH40: HSE Guidance note EH40 on Occupational Exposure Limits, to be used in conjunction with the COSHH regulations.
The information contained in this safety data sheet has been prepared using the best available information. However, in view of technical developments this may alter.
The material must only be used for its stated purpose and the information contained within this data sheet is offered solely for use in the evaluation of this product in respect of safety, health and environmental hazards.
Due to the many factors outside our control when using this product we cannot accept liability for any injury, accident, loss or damage caused through its use.
April 1999-09-07
BATH POTTERS SUPPLIES
MATERIAL SAFETY DATA SHEET
1. Identification of the preparation/Supplier reference
Trade Name Colemanite
Chemical name Colemanite
Synonyms None
Supplier
Bath Potters Supplies, Unit 18, Fourth Avenue, Westfield Trading Estate,
Radstock, Nr. Bath. BA3 4XE
Emergency numbers Tel: 01761 411077; Fax: 01761 414115
Internet: sales@bathpotters.co.uk
2. Composition
Component CAS EINECS % of composition
Colemenite standard 12291-65-5 100%
3. Health Hazard Identification
Inhalation
Excessive exposure may cause symptoms of chronic lung disease
Ingestion
The product is of low solubility in body fluids and it is likely to be of low acute toxicity
Eyes
May cause physical irritation and inflammation
Skin
The material is not a primary irritant but as with any abrasive powder it may give rise to minor irritation
4. First Aid Measures
Inhalation
Remove patient to fresh air, loosen tight clothing and seek medical attention
Ingestion
Do not induce vomiting, seek medical advice
Eyes
Wash immediately with copious amounts of water
Skin
Wash affected areas with water
5. Fire Fighting Measures
Extinguishing Media
It is compatible with standard fire fighting technique (e.g. use of water carbon dioxide, dry powder, sand and chemical foam extinguishers
Special Exposure hazard
None
Personal protective equipment
None other than required for surrounding fire condition
6. Accidental Release Measures
Leaks & Spills
Collect dry material by wet sweeping or vacuum with efficient particulate filter
Personal protective equipment
Respiratory protective equipment
7. Handling & Storage
Handling
Do not eat, drink, or smoke in areas where the material is used. Wash thoroughly
after handling the material
Storage
Store in dry area
8. Exposure Control/Personal protective Equipment
Engineering controls
Adequate ventilation should be provided so that Occupational Exposure Limits are not exceeded. Local Exhaust Ventilation is normally recommended
Personal protective equipment
Where LEV is not practicable and exposure is likely to be excessive, approved respiratory protection to CEN standards prEN 140, 141, 143 or 149 should be worn. Protective gloves and overalls are recommended for prolonged contact.
9. Physical & Chemical properties
Appearance & Odour
Odourless, off white powder
Flash point (ºC)
Not applicable
Flammability
Not known
Explosive properties
Non explosive
Oxidising properties
None
Specific gravity
2-3
pH value
9.3
Melting point (ºC)
930ºC* between 900ºC and 1180ºC
10. Stability & Reactivity
Chemical stability
The material is stable
Conditions/materials to avoid
Not known
Hazardous decomposition products
Not known
Hazardous polymerization products
None
11. Toxicology Information
Acute toxicology
LD50 oral (rats) >2000mg/kg
LD50 dermal not known
LD50 inhalation not known
Health effects
Prolonged or repeated exposure above occupational exposure standards may cause fibrosis of the lungs
12. Ecological information
Ecotoxicity
Not known
Persistence
The product is chemically stable and will persist in the environment
13. Disposal
Dispose in accordance with current waste Disposal regulations (for UK - Control of Pollution (Special Waste Regulations 1996). Landfill is the most appropriate method.
14. Transport Information
UN/SI No.
None
UN Class
Not restricted
Packing group
Not restricted
Road UK
Not restricted
ADR
Not restricted
Sea IMO
Not restricted
Air ICAO
Not restricted
15. Regulatory information
EC Supply Labelling
None required by directive 88/379/EEC
R-Phrases
None
S-Phrases
Optional for dusty powders
S20/21 when using do not eat, drink or smoke
S38 in case of insufficient ventilation wear suitable respiratory equipment
UK Occupational exposures limits*
Mg/m3 8 hr TWA % in product
* refer to HSE Guidance note EH40
In accordance with HSE Approved Code of Practice for CHIP, the recipient is reminded of their obligations under both the Health and Safety at Work Act (HSWA) and the Control of Substances Hazardous to Health Regulations (COSHH), and that the information in any safety data sheet does not constitutes the user's assessment of workplace risk
16. Other information
References
COSHH ACOP HSC approved Code of Practice for the Control of Substances
Hazardous to Health Regulations 1994
CHIP 96 Chemicals (Hazard Information and Packaging for Supply) Regulations
1996
CHIP SDS ACOPS HSC Approved Code of Practice for Safety data Sheets in accordance with
regulation 6 of the CHIP regulations
HSE EH40 HSE Guidance note EH40 on Occupational Exposure Limits to be used in
conjunction with the COSH regulations
Footnote
LIABILITY
Such information is the best of Bath Potters Supplies’ knowledge and belief accurate at the date of publication, which is the date generated automatically on the day of printing of this document. However, no representation, warranty of guarantee is made as to its accuracy, reliability of completeness. It is the user's responsibility to satisfy itself as to the suitability and completeness of such information for their own particular use.
THIRD PARTY MATERIALS
Insofar as materials not manufactured or supplied by Bath Potters Supplies are used in conjunction with, or instead of Bath Potters Supplies materials, it is the responsibility of the customer itself to obtain from the manufacturer or supplier all technical data and other properties relating to these and other materials and to obtain all necessary information relating to them. No liability can be accepted in respect of the use of Bath Potters Supplies materials in conjunctions with other materials.
17. National Legislation
UK Legislation
SI1993/1746 Chemicals (Hazard Information and Packaging) Regulations 1993
Environmental Protection (Duty of Care) regulations 1992 SI 2839
Carriage of Dangerous goods by Road and Rail Regulations 1994
Control of pollution Act 1974
Environmental Protection Act 1990
Highly Flammable Liquids and Petroleum Spirit Regulations 1972
EH40 Occupational Exposure Limits
SI1988/1657 The Control of Substances Hazardous to Health Regulations
Note - This is not an exhaustive list and users should satisfy themselves that they comply with all relevant National Regulations
Important notes
Design CHIP-002
The material must only be used for its stated purpose and the information contained within this data sheet is offered solely for use in the evaluation of this product in respect of safety, health and environmental hazards.
Further reference can be made to our standard terms and conditions of sale, a copy of which is available on request.
08 July 2002
Bath Potters' Supplies
MATERIAL SAFETY DATA SHEET
1. Identification of the preparation/Supplier reference
Trade Name F3110 High Soda Frit
Chemical name None
Synonyms None
Supplier
Bath Potters Supplies, Unit 18, Fourth Avenue, Westfield Trading Estate,
Radstock, Nr. Bath. BA3 4XE
Emergency numbers Tel: 01761 411077; Fax: 01761 414115
Internet: sales@bathpotters.co.uk
2. Composition
Component CAS EINECS % of composition
ceramic frit (ground) 65997-18-4 100%
3. Health Hazard Identification
Inhalation
Excessive exposure may cause symptoms of chronic lung disease
Ingestion
The product is of low solubility in body fluids and it is likely to be of low acute toxicity
Eyes
May cause physical irritation and inflammation
Skin
The material is not a primary irritant but as with any abrasive powder it may give rise to minor irritation
4. First Aid Measures
Inhalation
Remove patient to fresh air, loosen tight clothing and seek medical attention
Ingestion
Do not induce vomiting, seek medical advice
Eyes
Wash immediately with copious amounts of water
Skin
Wash affected areas with water
5. Fire Fighting Measures
Extinguishing Media
It is compatible with standard fire fighting technique (eg use of water carbon dioxide, dry powder, sand and chemical foam extinguishers
Special Exposure hazard
None
Personal protective equipment
None other than required for surrounding fire condition
6. Accidental Release Measures
Leaks & Spills
Collect dry material by wet sweeping or vacuum with efficient particulate
filter
Personal protective equipment
Respiratory protective equipment
7. Handling & Storage
Handling
Do not eat, drink, or smoke in areas where the material is used. Wash thoroughly after handling the material
Storage
Store in dry area
8. Exposure Control/Personal protective Equipment
Engineering controls
Adequate ventilation should be provided so that Occupational Exposure Limits are not exceeded. Local Exhaust Ventilation is normally recommended
Personal protective equipment
Where LEV is not practicable and exposure is likely to be excessive, approved respiratory protection to CEN standards prEN 140, 141, 143 or 149 should be worn. Protective gloves and overalls are recommended for prolonged contact.
9. Physical & Chemical properties
Appearance & Odour
Odourless, off white powder
Flash point (ºC)
Not applicable
Flammability
Not known
Explosive properties
Non explosive
Oxidising properties
None
Specific gravity
2-3
pH value
9.3
Melting point (ºC)
930ºC* between 900ºC and 1180ºC
10. Stability & Reactivity
Chemical stability
The material is stable
Conditions/materials to avoid
Not known
Hazardous decomposition products
Not known
Hazardous polymerization products
None
11. Toxicology Information
Acute toxicology
LD50 oral (rats) >2000mg/kg
LD50 dermal not known
LD50 inhalation not known
Health effects
Prolonged or repeated exposure above occupational exposure standards may cause fibrosis of the lungs
12. Ecological information
Ecotoxicity
Not known
Persistence
The product is chemically stable and will persist in the environment
13. Disposal
Dispose in accordance with current waste Disposal regulations (for UK - Control of Pollution (Special Waste Regulations 1996). Landfill is the most appropriate method.
14. Transport Information
UN/SI No.
None
UN Class
Not restricted
Packing group
Not restricted
Road UK
ADR
Not restricted
Not restricted
Sea IMO
Not restricted
Air ICAO
Not restricted
15. Regulatory information
EC Supply Labelling
None required by directive 88/379/EEC
R-Phrases
None
S-Phrases
Optional for dusty powders
S20/21 when using do not eat, drink or smoke
S38 in case of insufficient ventilation wear suitable respiratory equipment
UK Occupational exposures limits*
Mg/m3 8 hr TWA % in product
* refer to HSE Guidance note EH40
In accordance with HSE Approved Code of Practice for CHIP, the recipient is reminded of their obligations under both the Health and Safety at Work Act (HSWA) and the Control of Substances Hazardous to Health Regulations (COSHH), and that the information in any safety data sheet does not constitutes the user's assessment of workplace risk
16. Other information
References
COSHH ACOP HSC approved Code of Practice for the Control of Substances
Hazardous to Health Regulations 1994
CHIP 96 Chemicals (Hazard Information and Packaging for Supply) Regulations
1996
CHIP SDS ACOPS HSC Approved Code of Practice for Safety data Sheets in accordance with
regulation 6 of the CHIP regulations
HSE EH40 HSE Guidance note EH40 on Occupational Exposure Limits to be used in
conjunction with the COSH regulations
Footnote
LIABILITY
Such information is the best of Bath Potters' Supplies knowledge and belief accurate at the date of publication, which is the date generated automatically on the day of printing of this document. However, no representation, warranty of guarantee is made as to its accuracy, reliability of
completeness. It is the user's responsibility to satisfy itself as to the suitability and completeness of such information for their own particular use.
THIRD PARTY MATERIALS
Insofar as materials not manufactured or supplied by Bath Potters' Supplies are used in conjunction with, or instead of Bath Potters' Supplies materials, it is the responsibility of the customer itself to obtain from the manufacturer or supplier all technical data and other properties relating to these and other materials and to obtain all necessary information relating to them. No liability can be accepted in respect of the use of Bath Potters' Supplies materials in conjunctions with other materials.
17. National Legislation
UK Legislation
SI1993/1746 Chemicals (Hazard Information and Packaging) Regulations 1993
Environmental Protection (Duty of Care) regulations 1992 SI 2839
Carriage of Dangerous goods by Road and Rail Regulations 1994
Control of pollution Act 1974
Environmental Protection Act 1990
Highly Flammable Liquids and Petroleum Spirit Regulations 1972
EH40 Occupational Exposure Limits
SI1988/1657 The Control of Substances Hazardous to Health Regulations
Note - This is not an exhaustive list and users should satisfy themselves that they comply with all relevant National Regulations
Important notes
Design CHIP-002
The material must only be used for its stated purpose and the information contained within this data sheet is offered solely for use in the evaluation of this product in respect of safety, health and environmental hazards.
Further reference can be made to our standard terms and conditions of sale, a copy of which is available on request.
08 July 2002
Bath Potters' Supplies
MATERIAL SAFETY DATA SHEET
1. Identification of the preparation/Supplier reference
Trade Name Dry Ground High Alkaline Frit- 361187
Chemical name Frit.
Synonyms High Alkaline Frit, “T” Frit
Supplier
Bath Potters Supplies, Unit 18, Fourth Avenue, Westfield Trading Estate,
Radstock, Nr. Bath. BA3 4XE
Emergency numbers Tel: 01761 411077; Fax: 01761 414115
Internet: sales@bathpotters.co.uk
2. Composition
Component CAS EINECS % of composition
Frits, chemicals 65997-18-4 2660476 100
3. Health Hazard Identification
Inhalation Excessive exposure may cause damage to the lungs and kidneys.
Ingestion Product of low solubility in body fluids and likely to be of low acute toxicity.
Eyes May cause physical irritation and inflammation.
Skin Not a primary irritant. Any abrasive powder may give minor irritation.
4. First Aid Measures
Inhalation
Remove patient to fresh air, loosen tight clothing and seek medical attention.
Ingestion
Do not induce vomiting, seek medical advice.
Eyes
Wash immediately with copious amounts of water. Seek medical attention is irritation persists.
Skin
Wash affected areas with water. If irritation persists, seek medical attention
5. Fire Fighting Measures
Extinguishing Media
Suitable for surrounding fire conditions.
The product is not explosive or combustible. Standard fire fighting techniques only are required, i.e. water, sand, carbon dioxide, chemical foam extinguishers etc.
Special Exposure hazard
In the event of fire the product may emit harmful or toxic fumes.
Protective equipment
None other than required for surrounding fire conditions.
6. Accidental Release Measures
Leaks & Spills
Protective equipment
Remove dry materials either by a vacuum cleaner fitted with an efficient particulate filter or by damping down and scooping in to a receptacle.
Respiratory protective equipment.
7. Handling & Storage
Handling
Do not eat, drink, or smoke in areas where the material is used. Wash thoroughly after handling the material
Local exhaust ventilation is recommended to comply with occupational exposure limits (refer to Guidance Note EH40 - latest edition)
Storage
Store in dry area
8. Exposure Control/Personal protective Equipment
Engineering controls
Adequate ventilation should be provided so that Occupational Exposure Limits are not exceeded. Local Exhaust Ventilation is recommended
Personal protective equipment
Where LEV is not practicable and exposure is likely to be excessive, approved respiratory protection to CEN standards prEN 140, 141, 143 or 149 should be worn. Protective gloves and overalls are recommended for prolonged contact.
9. Physical & Chemical properties
Appearance & Odour
White powder, odourless
Flash point (ºC)
Not applicable
Flammability
Not applicable
Explosive properties
Non-explosive
Oxidising properties
Specific gravity
None
3-5
pH value
7 (Insoluble in water)
Melting point (ºC)
Not available
10. Stability & Reactivity
Chemical stability
The material is stable
Conditions/materials to avoid
None known
Hazardous decomposition products
None known
Hazardous polymerisation products
None
11. Toxicology Information
Acute toxicology
LD50 Oral >2000 mg/kg
LD50 Dermal Not known
LD50 Inhalation Not known
Health effects
Prolonged or repeated exposure above Occupational Exposure Standards may cause lung or kidney damage.
12. Ecological information
Ecotoxicity
Not known.
Persistence
Chemically stable and will persist in the environment.
13. Disposal
Dispose in accordance with current waste Disposal regulations (for UK - Control of Pollution (Special Waste) Regulations 1996). Landfill is the most appropriate method.
14. Transport Information
UN/SI No.
Not classified
UN Class
Not classified
Packing group
Not classified
Road UK ADR
Not classified
Not classified
Sea IMO
Not classified
Air ICAO
Not classified
15. Regulatory information
EC Supply Labelling
Harmful Xn
R-Phrases
R20/22 Harmful by inhalation and if swallowed.
R33 Danger of cumulative effects.
S-Phrases
S13 Keep away from food, drink and animal feeding stuffs.
S20/21 When using do not eat, drink or smoke.
S22/23 Do not breath dust or fumes/spray
S28 After contact with skin wash with plenty of water.
UK Occupational exposures limits*
Dusts: Total inhalable
respirable
Barium compounds (Ba)
Mg/m3 8 hr TWA % in product
10
5
0.5 5.5
* refer to HSE Guidance note EH40
In accordance with the H.S.E. Approved Code of Practice for CHIP, the recipient is reminded of their obligations under both the Health and Safety at Work Act (HSWA) and the Control of Substances Hazardous to Health Regulations (COSHH), and that the information in any safety data sheet does not constitute the user’s assessment of workplace risk.
16. Other information
General industrial hygiene practices are recommended when handling and using this product.
COSHH ACOP: H.S.C. Approved Code of Practice for the Control of Substances Hazardous to Health Regulations 1994.
CHIP 96: Chemicals (Hazard Information and Packaging for Supply) Regulations 1996.
CHIP SDS ACOP: H.S.C. Approved Code of Practice for Safety Data Sheets in accordance with regulation 6 of the CHIP regulations.
HSE EH40: HSE Guidance note EH40 on Occupational Exposure Limits, to be used in conjunction with the COSHH regulations.
The information contained in this safety data sheet has been prepared using the best available information. However, in view of technical developments this may alter.
The material must only be used for its stated purpose and the information contained within this data sheet is offered solely for use in the evaluation of this product in respect of safety, health and environmental hazards.
Due to the many factors outside our control when using this product we cannot accept liability for any injury, accident, loss or damage caused through its use.
April 1999-09-07
Bath Potters' Supplies
MATERIAL SAFETY DATA SHEET
1. Identification of the preparation/Supplier reference
Trade Name Lead Bisilicate
Chemical name None
Synonyms None
Supplier
Bath Potters Supplies, Unit 18, Fourth Avenue, Westfield Trading Estate,
Radstock, Nr. Bath. BA3 4XE
Emergency numbers Tel: 01761 411077; Fax: 01761 414115
Internet: sales@bathpotters.co.uk
2. Composition
Component CAS EINECS % of composition
frits, chemicals 65997-18-4 2660476 100
3. Health Hazard Identification
Inhalation : Excessive exposure may cause chronic lung disease and lead poisoning.
Ingestion : The product is of low solubility in body fluids and it is likely to be of low acute toxicity.
Eyes : May cause physical irritation and inflammation.
Skin : The material is not a primary irritant but as with any abrasive powder it may give rise
to minor irritation
4. First Aid Measures
Inhalation
Remove patient to fresh air, loosen clothing and seek medical attention.
Ingestion
Do not induce vomiting, seek medical advice.
Eyes
Wash immediately with copious amounts of water.
Skin
Wash affected areas with water.
5. Fire Fighting Measures
Extinguishing Media
Suitable for surrounding fire conditions.
Special Exposure hazard
In the event of fire, the product may emit harmful or toxic flumes
Protective equipment
Self-contained breathing apparatus.
6. Accidental Release Measures
Leaks & Spills
Use suitable vacuum equipment where reasonably practicable, otherwise damp down
and scoop into a receptacle.
Protective equipment
Respiratory protective equipment
7. Handling & Storage
Handling
Do not eat, drink, or smoke in areas where the material is used. Wash thoroughly after handling
the material
Storage
Store in a dry area
8. Exposure Control/Personal protective Equipment
Engineering controls
Adequate ventilation should be provided so that Occupational Exposure Limits arc not exceeded. Local Exhaust Ventilation is preferable to personal protection
Personal protective equipment
Where necessary, suitable personal protection should be used (e.g. overalls, gloves.
mask).
9. Physical & Chemical properties
Appearance & Odour
White crystal, odourless.
Flash point (ºC)
Not applicable
Flammability
Not applicable
Explosive properties
Non-explosive
Oxidising properties
None
Specific gravity
3-5
pH value
7 (Insoluble in water)
Melting point (ºC)
Not available.
10. Stability & Reactivity
Chemical stability
The material is stable.
Conditions/materials to avoid
None known
Hazardous decomposition products
None known
Hazardous polymerisation products
None
11. Toxicology Information
Acute toxicology
LD50 Oral >2000 mg/kg
LD50 Dermal Not known
LD50 Inhalation Not known
Health effects
Prolonged or repeated exposure above Occupational Exposure Standards, may cause Lead to accumulate in the body. In serious cases this may cause anaemia and damage to the kidneys and central nervous system. Lead in the blood of pregnant women may affect the development of the unborn child. Persons exposed to lead compounds should have regular health checks which should include Lead in Blood Monitoring.
12. Ecological information
Ecotoxicity
Not known
Persistence
The product is chemically stable and will persist in the environment.
13. Disposal
Dispose in accordance with current waste Disposal regulations (for UK - Control of Pollution (Special Waste) Regulations 1996). Landfill is the most appropriate method.
14. Transport Information
UN/SI No.
Not restricted
UN Class
Not restricted
Packing group
Not restricted
Road UK
ADR
Not restricted
Not restricted
Sea IMO
Not restricted
Air ICAO
Not restricted
15. Regulatory information
EC Supply Labelling
Toxic T
R-Phrases
R20/22 Harmful by inhalation and if swallowed.
R33 Danger of cumulative effects.
R61 May cause harm to the unborn child.
S-Phrases
S13 Keep away from food, drink and animal feeding stuffs.
S20/21 When using do not eat, drink or smoke.
S22/23 Do not breath dust or fumes/spray
UK Occupational exposures limits*
Lead compounds (as Pb)
Mg/m3 8 hr TWA % in product
0.15 58
* Refer to HSE Guidance note EH40
In accordance with the H.S.E. Approved Code of Practice for CHIP, the recipient is reminded of their obligations under both the Health and Safety at Work Act (HSWA) and the Control of Substances Hazardous to Health Regulations (COSHH), and that the information in any safety data sheet does not constitute the user’s assessment of workplace risk.
16. Other information
General industrial hygiene practices are recommended when handling and using this product.
COSHH ACOP: H.S.C. Approved Code of Practice for the Control of Substances Hazardous to Health Regulations 1994.
CHIP 96: Chemicals (Hazard Information and Packaging for Supply) Regulations 1996.
CHIP SDS ACOP: H.S.C. Approved Code of Practice for Safety Data Sheets in accordance with regulation 6 of the CHIP regulations.
HSE EH40: HSE Guidance note EH40 on Occupational Exposure Limits, to be used in conjunction with the COSHH regulations.
The information contained in this safety data sheet has been prepared using the best available information. However, in view of technical developments this may alter.
The material must only be used for its stated purpose and the information contained within this data sheet is offered solely for use in the evaluation of this product in respect of safety, health and environmental hazards.
Due to the many factors outside our control when using this product we cannot accept liability for any injury, accident, loss or damage caused through its use.
August 2000-08-18
Bath Potters' Supplies
MATERIAL SAFETY DATA SHEET
1. Identification of the preparation/Supplier reference
Trade Name Lead Sequisilicate Frit - 231030
Chemical name Frit.
Synonyms None.
Supplier
Bath Potters Supplies, Unit 18, Fourth Avenue, Westfield Trading Estate,
Radstock, Nr. Bath. BA3 4XE
Emergency numbers Tel: 01761 411077; Fax: 01761 414115
Internet: sales@bathpotters.co.uk
2. Composition
Component CAS EINECS % of composition
Frits, chemicals 65997-18-4 2660476 100
3. Health Hazard Identification
Inhalation Excessive exposure may cause chronic lung disease and lead poisoning.
Ingestion Product of low solubility in body fluids and likely to be of low acute toxicity.
Eyes May cause physical irritation and inflammation.
Skin Not a primary irritant. Any abrasive powder may give minor irritation.
4. First Aid Measures
Inhalation
Remove patient to fresh air, loosen tight clothing and seek medical attention.
Ingestion
Do not induce vomiting, seek medical advice.
Eyes
Wash immediately with copious amounts of water. Seek medical attention is irritation persists.
Skin
Wash affected areas with water. If irritation persists, seek medical attention
5. Fire Fighting Measures
Extinguishing Media
Suitable for surrounding fire conditions.
The product is not explosive or combustible. Standard fire fighting techniques only are required, i.e. water, sand, carbon dioxide, chemical foam extinguishers etc.
Special Exposure hazard
In the event of fire the product may emit harmful or toxic fumes.
Protective equipment
Self-contained breathing apparatus.
6. Accidental Release Measures
Leaks & Spills
Protective equipment
Remove dry materials either by a vacuum cleaner fitted with an efficient particulate filter or by damping down and scooping in to a receptacle.
Respiratory protective equipment.
7. Handling & Storage
Handling
Do not eat, drink, or smoke in areas where the material is used. Wash thoroughly after handling the material
Local exhaust ventilation is recommended to comply with occupational exposure limits (refer to Guidance Note EH40 - latest edition)
Storage
Store in dry area
8. Exposure Control/Personal protective Equipment
Engineering controls
Adequate ventilation should be provided so that Occupational Exposure Limits are not exceeded. Local Exhaust Ventilation is recommended
Personal protective equipment
Where LEV is not practicable and exposure is likely to be excessive, approved respiratory protection to CEN standards prEN 140, 141, 143 or 149 should be worn. Protective gloves and overalls are recommended for prolonged contact.
9. Physical & Chemical properties
Appearance & Odour
White powder, odourless
Flash point (ºC)
Not applicable
Flammability
Not applicable
Explosive properties
Non-explosive
Oxidising properties
Specific gravity
None
3-5
pH value
7 (Insoluble in water)
Melting point (ºC)
Not available
10. Stability & Reactivity
Chemical stability
The material is stable
Conditions/materials to avoid
None known
Hazardous decomposition products
None known
Hazardous polymerisation products
None
11. Toxicology Information
Acute toxicology
LD50 Oral Not known
LD50 Dermal Not known
LD50 Inhalation Not known
Health effects
Prolonged or repeated exposure above Occupational Exposure Standards may cause lead to accumulate in the body. In serious cases this may cause anaemia and damage to the kidneys and central nervous system. Lead in the blood stream of pregnant women may affect the unborn child. Persons exposed to lead compounds should have regular health checks which should include lead in blood monitoring,
12. Ecological information
Ecotoxicity
Not known.
Persistence
Chemically stable and will persist in the environment.
13. Disposal
Dispose in accordance with current waste Disposal regulations (for UK - Control of Pollution (Special Waste) Regulations 1996). Landfill is the most appropriate method.
14. Transport Information
UN/SI No.
Not classified
UN Class
Not classified
Packing group
Not classified
Road UK ADR
Not classified
Not classified
Sea IMO
Not classified
Air ICAO
Not classified
15. Regulatory information
EC Supply Labelling
Toxic T (in accordance with CHIP 2)
R-Phrases
R20/22 Harmful by inhalation and if swallowed.
R33 Danger of cumulative effects.
R61 May cause harm to the unborn child.
S-Phrases
S13 Keep away from food, drink and animal feeding stuffs.
S20/21 When using do not eat, drink or smoke.
S22/23 Do not breath dust or fumes/spray
UK Occupational exposures limits*
Lead compounds (as Pb)
Mg/m3 8 hr TWA % in product
0.15 63%
* refer to HSE Guidance note EH40
All products containing lead compounds are subject to the Control of Lead at Work Regulations 1980, via the H.S.C. Approved Code of Practice 1985.
In accordance with the H.S.E. Approved Code of Practice for CHIP, the recipient is reminded of their obligations under both the Health and Safety at Work Act (HSWA) and the Control of Substances Hazardous to Health Regulations (COSHH), and that the information in any safety data sheet does not constitute the user’s assessment of workplace risk.
16. Other information
General industrial hygiene practices are recommended when handling and using this product.
COSHH ACOP: H.S.C. Approved Code of Practice for the Control of Substances Hazardous to Health Regulations 1994.
CHIP 96: Chemicals (Hazard Information and Packaging for Supply) Regulations 1996.
CHIP SDS ACOP: H.S.C. Approved Code of Practice for Safety Data Sheets in accordance with regulation 6 of the CHIP regulations.
HSE EH40: HSE Guidance note EH40 on Occupational Exposure Limits, to be used in conjunction with the COSHH regulations.
The information contained in this safety data sheet has been prepared using the best available information. However, in view of technical developments this may alter.
The material must only be used for its stated purpose and the information contained within this data sheet is offered solely for use in the evaluation of this product in respect of safety, health and environmental hazards.
Due to the many factors outside our control when using this product we cannot accept liability for any injury, accident, loss or damage caused through its use.
April 1999-09-07
BATH POTTERS SUPPLIES
MATERIAL SAFETY DATA SHEET
1. Identification of Preparation/Company.
Trade name : Low Expansion Frit
Chemical name : borosilicate glass
Synonyms : borosilicate frit, w/g leadless transparent frit
Supplier
Bath Potters Supplies, Unit 18, Fourth Avenue, Westfield Trading Estate,
Radstock, Nr. Bath. BA3 4XE
Emergency numbers Tel: 01761 411077; Fax: 01761 414115
Internet: sales@bathpotters.co.uk
2. Composition.
Component C.A.S. EINECS % of composition
A single borosilicate glass frit of no specific significant hazards …treat it as nuisance dust.
3. Health Hazard Identification.
Inhalation : Excessive exposure may cause symptoms of chronic lung disease.
Ingestion : The product is of low solubility in body fluids and it is likely to be of
low acute toxicity.
Eyes : May cause physical irritation and inflammation.
Skin : The material is not a primary irritant, but as with any abrasive powder
it may give rise to minor irritation.
4. First Aid Measures.
Inhalation : Remove patient to fresh air, loosen clothing, seek medical attention.
Ingestion : Do not induce vomiting, seek medical advice.
Eyes : Wash immediately with copious amounts of water.
Skin : Wash affected areas with water.
5. Fire-fighting Measures.
Extinguishing media : Suitable for surrounding fire conditions.
Special exposure hazard : None.
Personal protective equipment : None other than required for surrounding fire conditions.
6. Accidental Release Measures.
Leaks & spills : Use suitable vacuum equipment where reasonably practicable,
otherwise damp down and scoop into a receptacle.
Personal protective equipment : Respiratory protective equipment.
7. Handling & Storage.
Handling : Do not eat, drink, or smoke in areas where the material is used.
Wash thoroughly after handling the material.
Storage : Store in a dry area.
8. Exposure Controls/Personal Protective Equipment.
Engineering controls : Adequate ventilation should be provided so that Occupational
Exposure Limits are not exceeded.
Local Exhaust Ventilation is preferable to personal protection.
Personal protective equipment: Where necessary, suitable personal protection should be used
(e.g. overalls, gloves, mask).
9. Physical & Chemical Properties.
Appearance & odour : white powder, odourless.
Flash point (°C) : Not applicable.
Flammability : Not applicable.
Explosive properties : Non-explosive.
Oxidising properties : None
Specific gravity : 3-5.
pH value : 7 (Insoluble in water)
Melting point (°C) : Not available.
10. Stability & Reactivity.
Chemical stability : The material is stable.
Conditions/materials to avoid : None known.
Hazardous decomposition products : None known.
Hazardous polymerization products : None.
11. Toxicological Information.
Acute toxicity :- LD50 Oral (rat) Not known.
LD50 Dermal Not known.
LC50 Inhalation Not known.
Health effects : Prolonged or repeated exposure above Occupational Exposure Limits may cause
fibrosis of the lungs.
12. Ecological Information.
Ecotoxicity : Not known.
Persistence : The product is chemically stable and will persist in the environment.
13. Disposal.
Dispose of in accordance with current Waste Disposal Regulations
(for U.K. ... Special Waste Regulations 1996).
Landfill is the most appropriate method.
14. Transport Information.
U.N./S.I. No. : Not restricted.
U.N. Class : Not restricted.
Packing group : Not restricted.
Road :- U.K. : Not restricted.
A.D.R. : Not restricted.
Sea:- I.M.O. : Not restricted.
Air:- I.C.A.O. : Not restricted.
15. Regulatory Information.
EC Supply labelling: None required by relevant EU directives and UK regulations.
R-Phrases : None.
S-Phrases : S22 Do not breathe dust.
U.K Occupational exposure limits*: mg/m3 8 hr TWA % in product (total dust)
Dusts:
Total inhalable 10
respirable 4
* Refer to H.S.E. Guidance note EH40.
In accordance with the H.S.E. Approved Code of Practice for CHIP, the recipient is reminded of their
obligations under both the Health and Safety at Work Act (HSWA) and the Control of Substances
Hazardous to Health Regulations (COSHH), and that the information in any safety data sheet does not
constitute the user's assessment of workplace risk.
16. Other Information.
References :
ADR European agreement concerning international transport of dangerous goods by road
(Accord europeen relatif au transport international des marchandises Dangereuses par Route).
CAS International reference numbers for chemical substances (Chemical Abstracts Service).
CHIP Chemicals (Hazard Information and Packaging) regulations 1993, and later revisions.
CHIP SDS ACOP H.S.C. Approved Code Of Practice for Safety Data Sheets in accordance with
regulation 6 of the CHIP regulations.
COSHH ACOP H.S.C. Approved Code Of Practice for the Control Of Substances Hazardous to Health
regulations 1988, and later revisions.
EINECS European INventory of Existing commercial Chemical Substances.
HSE EH40 H.S.E. Guidance note EH40 on Occupational Exposure Limits (revised annually),
to be used in conjunction with the COSHH regulations.
HSWA Health and Safety at Work Act 1974.
ICAO International Civil Aviation Organisation.
IMO International Maritime Organisation.
LC50 Concentration which is lethal by inhalation to 50% of a defined population (eg: rats)
within a specified time.
LD50 Dose which is lethal orally or dermally to 50% of a defined population (eg: rats)
within a specified time.
UN United Nations.
Design : CHIP-000 Date Created : 06/11/2000
Issue No. : 8 Revisions : sections 1, 11, 15, 16.
Since the specific conditions of use of the product are outside the control of the supplier, the user is responsible for
ensuring that the requirements of relevant legislation are complied with. The information within this safety data sheet
is correct to the best of our knowledge and information at the date of publication. The information relates only to the
specific product designated and may not be valid for the product if used in combination with any products or any
processes other than those specified in the text.
PRINT DATE… 11.07.2002
Bath Potters' Supplies
MATERIAL SAFETY DATA SHEET
1. Identification of the preparation/Supplier reference
Trade Name Frits
P2953
P2954
P2955 (J) Standard
Borax
P2957
P2958
P2959
P2960
P2961 StandardAlkaline
P2963
P2964
P3110
P3311*
R1122
Chemical name None
Synonyms None
Supplier
Bath Potters Supplies, Unit 18, Fourth Avenue, Westfield Trading Estate,
Radstock, Nr. Bath. BA3 4XE
Emergency numbers Tel: 01761 411077; Fax: 01761 414115
Internet: sales@bathpotters.co.uk
4
2. Composition
Component CAS EINECS % of composition
*colemenite standard 12291-65-5 100%
ceramic frit (ground) 65997-18-4 100%
3. Health Hazard Identification
Inhalation Excessive exposure to any dusty residue may cause irritation of the respiratory tract and mucous membranes, and cause symptoms of chronic lung disease.
Ingestion The product is of low solubility in body fluids and likely to be of low acute toxicity.
Eyes May cause physical irritation and inflammation.
Skin The product is classed as a minor irritant, but as with any abrasive powder it may cause minor irritation and/or sensitisation.
4. First Aid Measures
Inhalation
Remove patient to fresh air, loosen tight clothing and seek medical advice if irritation persists.
Ingestion
Do not induce vomiting, rinse mouth with water (provided patient is conscious). Seek medical advice if irritation persists, or if ingestion was particularly large.
Eyes
Irrigate immediately with copious amounts of water for 15 minuets, paying particular attention to under the eyelid. Seek medical attention is irritation persist.
Skin
Remove contaminated clothing and wash affected areas with soap and water. If irritation persists, seek medical attention
5. Fire Fighting Measures
Extinguishing Media
Suitable for surrounding fire conditions. The product is not explosive or combustible. Standard fire fighting techniques only are required, i.e. water, sand, carbon dioxide, chemical foam extinguishers etc.
Special Exposure hazard
None
Protective equipment
None other than required for surrounding fire conditions
6. Accidental Release Measures
Leaks & Spills
Remove dry materials either by a vacuum cleaner fitted with an efficient particulate filter or by damping down and scooping in to a receptacle. Small spillages may be washed into drains with plenty of water (provided effluent consent conditions are complied with).
Protective equipment
Respiratory protective equipment.
7. Handling & Storage
Handling
Do not eat, drink, or smoke in areas where the material is used. Wash thoroughly after handling the material. Local exhaust ventilation is recommended to comply with occupational exposure limits (refer to Guidance Note EH40 - latest edition)
Storage
Store in a sealed container in normal dry conditions.
8. Exposure Control/Personal protective Equipment
Engineering controls
Adequate ventilation should be provided so that Occupational Exposure Limits are not exceeded. Local Exhaust Ventilation is normally recommended
Personal protective equipment
Where LEV is not practicable and exposure is likely to be excessive, approved respiratory protection to CEN standards prEN 140, 141, 143 or 149 should be worn. Protective gloves and overalls are recommended for prolonged contact.
9. Physical & Chemical properties
Appearance & Odour
Odourless, off white powder
Flash point (ºC)
Not applicable
Flammability
Not applicable
Explosive properties
Non-explosive
Oxidising properties
None
Specific gravity
2-3
pH value
9.3
Melting point (ºC)
930ºC* between 900ºC and 1180ºC
10. Stability & Reactivity
Chemical stability
The material is stable in normal atmospheric conditions.
Conditions/materials to avoid
Contact with moisture will hydrate the product.
Hazardous decomposition products
None known
Hazardous polymerisation products
None known
11. Toxicology Information
Acute toxicology
LD50 Oral Not known
LD50 Dermal Not known
LD50 Inhalation Not known
Health effects
Prolonged or repeated exposure to any dust, above Occupational Exposure Standards, may cause fibrosis of the lungs.
12. Ecological information
Ecotoxicity
Chemically inert, and does not react readily with most common substances at room temperatures and pressures.
Persistence
The product is essentially insoluble in water and is not expected to present a hazard.
13. Disposal
Dispose in accordance with current waste Disposal regulations (for UK - Control of Pollution (Special Waste) Regulations 1980). Landfill is the most appropriate method. Small amounts may be washed into drains with plenty of water, but observe local effluent control limits.
14. Transport Information
UN/SI No.
Not classified
UN Class
Not classified
Packing group
Not classified
Road UK ADR
Not classified
Not classified
Sea IMO
Not classified
Air ICAO
Not classified
15. Regulatory information
EC Supply Labelling
None required by directive 88/379/EEC, and subsequent amendments.
R-Phrases
None
S-Phrases
Optional for dusty powders:
S20/21 When using do not eat, drink or smoke.
S22/23 Do not breath dust or fumes/spray
S38 In case of insufficient ventilation wear suitable respiratory equipment.
UK Occupational exposures limits*
Dusts: Total inhalable
respirable
Mg/m3 8 hr TWA % in product
10
5
* Refer to HSE Guidance note EH40
In accordance with the H.S.E. Approved Code of Practice for CHIP, the recipient is reminded of their obligations under both the Health and Safety at Work Act (HSWA) and the Control of Substances Hazardous to Health Regulations (COSHH), and that the information in any safety data sheet does not constitute the user’s assessment of workplace risk.
16. Other information
Summary per product
P2953 borax frit
P2954 calcium borate frit
P2955 borax frit (J Frit)
P2956 opaque zircon frit
P2957 borax frit
P2958 borax frit
P2959 high temperature borax frit
P2960 low expansion frit
P2961 standard alkaline frit
P2963 soft alkaline frit
P2964 soft borax frit
P3110 Ferro frit (high Soda)
P3311 Colemanite
R1122 white zircon/borax frit
General industrial hygiene practices are recommended when handling and using this product.
COSHH ACOP: H.S.C. Approved Code of Practice for the Control of Substances Hazardous to Health Regulations 1994.
CHIP 96: Chemicals (Hazard Information and Packaging for Supply) Regulations 1996.
CHIP SDS ACOP: H.S.C. Approved Code of Practice for Safety Data Sheets in accordance with regulation 6 of the CHIP regulations.
HSE EH40: HSE Guidance note EH40 on Occupational Exposure Limits, to be used in conjunction with the COSHH regulations.
The information contained in this safety data sheet has been prepared using the best available information. However, in view of technical developments this may alter.
The material must only be used for its stated purpose and the information contained within this data sheet is offered solely for use in the evaluation of this product in respect of safety, health and environmental hazards.
Due to the many factors outside our control when using this product we cannot accept liability for any injury, accident, loss or damage caused through its use.
August 2000-08-18
BATH POTTERS SUPPLIES
MATERIAL SAFETY DATA SHEET
1. Identification of Preparation/Company.
Trade name : Soft Borax Frit
Chemical name : borosilicate glass
Synonyms : borosilicate frit, w/g leadless transparent frit
Supplier
Bath Potters Supplies, Unit 18, Fourth Avenue, Westfield Trading Estate,
Radstock, Nr. Bath. BA3 4XE
Emergency numbers Tel: 01761 411077; Fax: 01761 414115
Internet: sales@bathpotters.co.uk
2. Composition.
Component C.A.S. EINECS % of composition
A single borosilicate glass frit of no specific significant hazards …treat it as nuisance dust.
3. Health Hazard Identification.
Inhalation : Excessive exposure may cause symptoms of chronic lung disease.
Ingestion : The product is of low solubility in body fluids and it is likely to be of
low acute toxicity.
Eyes : May cause physical irritation and inflammation.
Skin : The material is not a primary irritant, but as with any abrasive powder
it may give rise to minor irritation.
4. First Aid Measures.
Inhalation : Remove patient to fresh air, loosen clothing, seek medical attention.
Ingestion : Do not induce vomiting, seek medical advice.
Eyes : Wash immediately with copious amounts of water.
Skin : Wash affected areas with water.
5. Fire-fighting Measures.
Extinguishing media : Suitable for surrounding fire conditions.
Special exposure hazard : None.
Personal protective equipment : None other than required for surrounding fire conditions.
6. Accidental Release Measures.
Leaks & spills : Use suitable vacuum equipment where reasonably practicable,
otherwise damp down and scoop into a receptacle.
Personal protective equipment : Respiratory protective equipment.
7. Handling & Storage.
Handling : Do not eat, drink, or smoke in areas where the material is used.
Wash thoroughly after handling the material.
Storage : Store in a dry area.
8. Exposure Controls/Personal Protective Equipment.
Engineering controls : Adequate ventilation should be provided so that Occupational
Exposure Limits are not exceeded.
Local Exhaust Ventilation is preferable to personal protection.
Personal protective equipment: Where necessary, suitable personal protection should be used
(e.g. overalls, gloves, mask).
9. Physical & Chemical Properties.
Appearance & odour : white powder, odourless.
Flash point (°C) : Not applicable.
Flammability : Not applicable.
Explosive properties : Non-explosive.
Oxidising properties : None
Specific gravity : 3-5.
pH value : 7 (Insoluble in water)
Melting point (°C) : Not available.
10. Stability & Reactivity.
Chemical stability : The material is stable.
Conditions/materials to avoid : None known.
Hazardous decomposition products : None known.
Hazardous polymerization products : None.
11. Toxicological Information.
Acute toxicity :- LD50 Oral (rat) Not known.
LD50 Derma | 
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